Here goes to add an OU for AAD Connect sync.
1. Open AAD Connect Synchronization Service Manager
2. Select on-prem AD connector and click Properties
3. Configure Directory Partitions -> Containers
4. Enter Password and click OK
5. Select an OU to be added, "AAD Connect" in this example
6. Create an user for test
7. A new user, "new_aad" created
8. "new_aad" not listed in O365 portal
9. Start AAD sync "Delta"
10. "new_aad" is synced/listed in O365 portal
This is not recommended because next time the AD Wizard is run it is Not aware of these OU changes and reverts back to the latest Synced OU's that where selected in the AD Wizard
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